Tuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood.

نویسندگان

  • S Van den Bosch
  • W Schutyser
  • S-F Koelewijn
  • T Renders
  • C M Courtin
  • B F Sels
چکیده

Liquid reductive processing of birch wood in the presence of commercial Ru/C or Pd/C catalysts yields about 50% of a select set of phenolic monomers and a variety of phenolic di- and oligomers, next to a solid carbohydrate pulp. Changing the catalyst from Ru/C to Pd/C drastically increases the OH-content of the lignin-derived products, in particular for the phenolic monomers.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Lignin Hydrogenolysis: Improving Lignin Disassembly through Formaldehyde Stabilization

Lignocellulosic biomass is available in large quantities and constitutes an attractive feedstock for the sustainable production of bulk and fine chemicals. Although methods have been established for the conversion of its cellulosic fractions, valorization of lignin has proven to be challenging. The difficulty in disassembling lignin originates from its heterogeneous structure and its propensity...

متن کامل

High Catalytic Efficiency of Lignin Depolymerization over Low Pd-Zeolite Y Loading at Mild Temperature

This article reported a novel low-temperature process for aromatics production through lignin depolymerization catalyzed by 0.1 wt% Pd-zeolite Y catalyst prepared by a facile method. Under the same reactive condition, the as-prepared Pd-zeolite Y catalysts exhibited much higher catalytic efficiency than zeolite Y or commercial Pd/Al2O3–zeolite composites. The selectivity of the Pd-zeolite Y tow...

متن کامل

Comprehensive Transcriptome Analysis of Developing Xylem Responding to Artificial Bending and Gravitational Stimuli in Betula platyphylla

Betula platyphylla Suk (birch) is a fast-growing woody species that is important in pulp industries and the biofuels. However, as an important pulp species, few studies had been performed on its wood formation. In the present study, we investigated the molecular responses of birch xylem to artificial bending and gravitational stimuli. After trunks of birch trees were subjected to bending for 8 ...

متن کامل

Hydrogen transfer from supercritical methanol over a solid base catalyst: a model for lignin depolymerization.

A (super)critical transfer: The consecutive hydrogenolysis and hydrogenation of the lignin model compound dihydrobenzofuran was studied in supercritical methanolic solutions using porous metal oxide catalysts. These catalysts promote H(2) production from methanol followed by hydrogenolysis of the ether linkages and reduction of the aromatic rings, leading principally to a mixture of cyclohexanols.

متن کامل

Selective production of arenes via direct lignin upgrading over a niobium-based catalyst

Lignin is the only large-volume renewable source of aromatic chemicals. Efficient depolymerization and deoxygenation of lignin while retaining the aromatic functionality are attractive but extremely challenging. Here we report the selective production of arenes via direct hydrodeoxygenation of organosolv lignin over a porous Ru/Nb2O5 catalyst that enabled the complete removal of the oxygen cont...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 51 67  شماره 

صفحات  -

تاریخ انتشار 2015